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05.5.1 / Moisture

Heterogeneous moisture diffusion

Predict water uptake or release through a multi-material laminate using per-ply diffusivity, saturation, independent moisture boundaries, and the same interpolated process time grid used by heat transfer. Expand any equation for its physical meaning, variables, units, model connection, and theory source.

Fickian continuum model

Eq. 05.5.1-01One-dimensional moisture balance
∂C/∂t = ∂/∂z [D(T,z) ∂C/∂z]
Equation detailsExplanation · variables · model connection · reference

Applies Fick’s second law through the laminate thickness. The divergence form permits temperature- and ply-dependent diffusivity while preserving concentration flux at material interfaces.

VariablesC(z,t)local moisture concentration stored by the laminate modelpercentage pointsD(T,z)local through-thickness diffusivitym²/szthrough-thickness coordinatemtprocess or exposure times

Model connectionSolved on the same cell-centered mesh and time grid as heat transfer. The current temperature field updates D before the moisture equation is advanced.

Theory basisNASA moisture diffusion in composites

Eq. 05.5.1-02Arrhenius diffusivity
D(T,z) = D0(z) exp[−ED(z)/(R T)]
Equation detailsExplanation · variables · model connection · reference

Adjusts each ply’s reference diffusivity for the current absolute temperature using a calibrated activation energy.

VariablesD(T,z)temperature-dependent ply diffusivitym²/sD0(z)ply diffusivity prefactorm²/sED(z)diffusion activation energyJ/molRuniversal gas constant8.314462618 J/(mol·K)Tlocal nodal absolute temperatureK

Model connectionEvaluated after the thermal solve in each staggered process iteration; different plies may use different D0 and ED values.

Theory basisTemperature-dependent environmental diffusion

Heterogeneous finite-volume form

Eq. 05.5.1-03Harmonic moisture face conductance
Hi+1/2 = [Δzi/(2Di) + Δzi+1/(2Di+1)]−1
Equation detailsExplanation · variables · model connection · reference

Adds the adjacent half-cell diffusion resistances in series, conserving interfacial moisture flux across dissimilar ply materials.

VariablesHi+1/2moisture conductance across a shared cell facem/sDi, Di+1diffusivities in adjacent cellsm²/sΔzi, Δzi+1adjacent cell thicknessesm

Model connectionPopulates the moisture transport operator. A zero diffusivity on either side closes that interface in the current reduced-order model.

Theory basisLayered-composite diffusion treatment

Eq. 05.5.1-04Semidiscrete moisture balance
ΔzidCi/dt = Hi+1/2(Ci+1−Ci) − Hi−1/2(Ci−Ci−1)
Equation detailsExplanation · variables · model connection · reference

Balances concentration storage in a cell with the moisture flux entering and leaving through its two faces.

VariablesCicell-center concentrationpercentage pointsΔzicell storage thickness per unit areamHi±1/2left and right moisture face conductancesm/s

Model connectionAssembled into the same theta-family integrator as the thermal equation, but with cell thickness rather than heat capacity as the storage matrix.

Theory basisFickian layered finite-difference/volume balance

Independent moisture boundaries

Eq. 05.5.1-05Moisture surface boundary operators
Prescribed: Hs = 2D/Δz,   SC,s = HsCsInsulated: Hs = 0,   SC,s = 0Film: Hs = [Δz/(2D)+1/hm]−1,   SC,s = HsCsCustom inward flux: Hs = 0,   SC,s = Jin
Equation detailsExplanation · variables · model connection · reference

Writes prescribed concentration, insulated, film-transfer, and custom inward-flux conditions as a conductance and source on the surface control volume.

VariablesHseffective surface moisture conductancem/sSC,ssurface concentration-flux sourcepercentage-point·m/sCsscheduled surface or environmental moisturepercentage pointshmmoisture film-transfer coefficientm/sJinuser-defined signed inward concentration fluxpercentage-point·m/sD, Δzsurface-cell diffusivity and thicknessm²/s, m

Model connectionTop and bottom selections are independent and are interpolated from columns 3, 5, and 7 of their respective surface tables.

Theory basisComposite environmental-exposure boundary modeling

Eq. 05.5.1-06Theta moisture integration
[S/Δt + θCKCn+1]Cn+1 = [S/Δt − (1−θC)KCn]Cn + Jn+θ
Equation detailsExplanation · variables · model connection · reference

Advances the heterogeneous diffusion system while allowing fully implicit or Crank–Nicolson weighting of the old and new operators and boundary sources.

VariablesSdiagonal moisture storage matrix of cell thicknessesmKCn, KCn+1old and new diffusion-plus-boundary matricesm/sCn, Cn+1old and new concentration vectorspercentage pointsJn+θtheta-weighted boundary source vectorpercentage-point·m/sθCmoisture time-integration parameterdimensionless, 0–1Δttransport time steps

Model connectionExecuted only when the moisture-diffusion flag is active. The solved field is clipped to nonnegative values and, where supplied, each node’s ply saturation limit.

Theory basisTransient Fickian diffusion solution

Eq. 05.5.1-07Physical concentration bounds
Cin+1 = min[Csat,i, max(0,Ci*)]
Equation detailsExplanation · variables · model connection · reference

Prevents negative concentration and limits each node to its calibrated saturation concentration when a positive saturation value is supplied.

VariablesCi*unbounded concentration returned by the linear solvepercentage pointsCsat,isaturation concentration of the node’s ply materialpercentage pointsCin+1accepted bounded concentrationpercentage points

Model connectionApplied node-by-node after each moisture solve. When Csat is zero or omitted, only the nonnegative lower bound is imposed.

Theory basisEquilibrium moisture-content context

Hygroscopic strain coupling

Concentration is stored in percentage points to match the coefficient of moisture expansion used by the laminate model. Every ply may carry its own β1, β2, and β3.

Eq. 05.5.1-08Local moisture free strain
εMk(z,t) = βk ΔCk(z,t)
Equation detailsExplanation · variables · model connection · reference

Maps moisture change relative to the ply reference state into unconstrained hygroscopic strain in each local material direction.

VariablesεMkmoisture free strain in local direction kstrainβkcoefficient of moisture expansionstrain per percentage pointΔCklocal moisture change from the reference statepercentage pointsklocal ply material direction 1, 2, or 3index

Model connectionThe nodal field is fitted across each ply and optionally included in process resultants, local/global field recovery, and ply failure checks.

Theory basisNASA hygrothermal laminate mechanics

Scope boundary. The model is one-dimensional and Fickian. Edge drying, damage-assisted transport, two-stage sorption, concentration-dependent diffusivity, imperfect ply-interface partitioning, and stress-assisted diffusion require extension or calibrated effective parameters.

Theory references

  1. NASA composite moisture-diffusion formulation and environmental response reference.
  2. NASA, Prediction of moisture and temperature changes in composites during atmospheric exposure.
  3. Nettles, Basic Mechanics of Laminated Composite Plates, NASA RP-1351, including hygrothermal effects.

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